Rare Earth Ion Size Effects in Structures of Rare Earth N,N′‐bis(2‐trifluoromethylphenyl)formamidinates

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Analysis uncovers tetradentate configurations in rare earth complexes, suggesting unique bonding models.

The tetradentate CF3 Form ligands maximize interactions with rare earth metals, indicating stability.
Two rare earth complexes were characterized using 1 H NMR and 19 F NMR spectroscopy for metallic configurations.
X‐ray crystallography revealed distinct coordination numbers for Ce and Y in complex structures, facilitating understanding of bonding.
The findings call for further investigation into ligand arrangement effects on recovery methods for rare earth elements.

Werner et al. (2025) studied this question.

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