Rh(iii) catalyzed C–H activation achieves isoquinoline synthesis via [4 + 1] and [4 + 2] annulations, indicating a new synthetic strategy.
A Rh( iii ) catalyzed perimidine directed C–H activation strategy to achieve [4 + 1] and [4 + 2] annulations with two distinct classes of alkenes for the synthesis of perimidine-linked spiro-succinimides and isoquinolines has been developed.
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Kumari et al. (2025) studied this question.
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