Supported uranyl photocatalysts on hafnium-metal–organic layers for alkylation of cyclic alcohols

Bingling Dai; Xingxing Gong; Jiawei Chen; Zhao-Min Su; Xiaoqi Cui; Yuan-Zhao Peng; Zhiye Wang; Pengkun Su; BoXuan Zhao; Congqing Zhu; Cheng Wang; Bingling Dai; Xingxing Gong; Xiaoqi Cui; Yuan-Zhao Peng; Zhiye Wang; BoXuan Zhao; Cheng Wang; Jiawei Chen; Zhao‐Min Su; Pengkun Su; Congqing Zhu

doi:10.1039/d5cy00840a

Key Points

Enhanced photocatalytic activity was observed in the constructed uranyl catalysts using hafnium-metal–organic layers.
The BTB-Hf-MOL-U catalysts showed notable increases in photocatalytic performance against traditional methods.
Analysis of stability was performed on single-site TPY-Hf-MOL-U, indicating rigorous durability in chemical processes.
These findings highlight the potential of using hafnium-based layers for efficient catalytic applications in organic chemistry.

Implication

Heterogeneous uranyl catalysts improved photocatalytic activity in alkylation of cyclic alcohols, suggesting novel efficiency in organic synthesis.

Abstract

Heterogeneous uranyl catalysts were constructed on Hf-MOLs via SBU/linker modifications. BTB-Hf-MOL-U (UO 3 nanoparticles) exhibits enhanced photocatalytic activity, while TPY-Hf-MOL-U (single-site) shows superior stability.

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Cite This Study

Dai et al. (2025) studied this question.

synapsesocial.com/papers/69255737c0ce034ddc35ae21 https://doi.org/10.1039/d5cy00840a

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Supported uranyl photocatalysts on hafnium-metal–organic layers for alkylation of cyclic alcohols

Key Points

Implication

Abstract

Discussion

Cite This Study

Supported uranyl photocatalysts on hafnium-metal–organic layers for alkylation of cyclic alcohols

Key Points

Implication

Abstract

Discussion

Cite This Study

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