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December 12, 2025Organic Letters4 citations

Modular Synthesis of Heptagon-Embedded Polyarenes by Double Cyclizations with Pyrones-Derived Aryliodonium Salts

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CPCheng PanXLXiaoting LiuLWLimin Wang

Key Points

  • To explore a new synthetic approach for heptagon-embedded polyarenes.
  • Utilized double cyclization technique
  • Employed pyrones-derived aryliodonium salts
  • Focused on the synthesis of dibenzoheptanaphthalene frameworks
  • Introduced an efficient construction method for heptagon-embedded polyarenes
  • Showed relevance in optoelectronic material applications

Abstract

Heptagon-embedded polyarenes have long been of great interest in the field of optoelectronic materials. Herein, we report a double-cyclization strategy for the synthesis of heptagon-embedded polyarenes via pyrones-derived aryliodonium salts, enabling the efficient construction of dibenzoheptanaphthalene frameworks.

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Cite This Study

Pan et al. (2025) studied this question.

synapsesocial.com/papers/694019192d562116f28f6718https://doi.org/10.1021/acs.orglett.5c04867
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