Crystallographic Evidence of a Trinuclear (salen)Manganese(IV/III/IV)-μ-Oxo Formed during Catalytic C(sp3)–H Oxidation Reactions

Bhaswati Paul; Kusalvin Dabare; Joshua D. Bocarsly; L. Reginald Mills

doi:10.1039/d5dt02844b

December 11, 2025Dalton TransactionsOpen Access

Crystallographic Evidence of a Trinuclear (salen)Manganese(IV/III/IV)-μ-Oxo Formed during Catalytic C(sp3)–H Oxidation Reactions

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Key Points

The research focuses on synthesizing manganese-oxo catalysts for C(sp3)–H bond oxidation.
Targeted synthesis of (salen/salophen)manganese complexes
Variation of axial ligand identity
Examining different oxidation states of manganese
Identification of trinuclear (salen) manganese complexes
Characterization of μ-Oxo formation
Demonstrated efficient catalytic activity in C(sp3)–H oxidation

Implication

Exploration of manganese-oxo catalysts improved oxidation state in C(sp3)–H bond reactions, indicating potent catalytic activity.

Abstract

The formation of manganese-oxo catalysts involved in C(sp3)–H bond oxidation was explored in the targeted synthesis of (salen/salophen)manganese complexes that varied axial ligand identity and varied oxidation state of the...

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Cite This Study

Paul et al. (2025) studied this question.

synapsesocial.com/papers/6940192a2d562116f28f6bb7 https://doi.org/10.1039/d5dt02844b

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Crystallographic Evidence of a Trinuclear (salen)Manganese(IV/III/IV)-μ-Oxo Formed during Catalytic C(sp3)–H Oxidation Reactions

Key Points

Implication

Abstract

Discussion

Cite This Study

Crystallographic Evidence of a Trinuclear (salen)Manganese(IV/III/IV)-μ-Oxo Formed during Catalytic C(sp3)–H Oxidation Reactions

Key Points

Implication

Abstract

Discussion

Cite This Study

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