An Optimized Approach for Methane Spectral Feature Extraction Under High-Humidity Conditions

Fourier transform infrared (FTIR) spectroscopy-based gas remote sensing has been widely applied for long-range atmospheric composition analysis. However, when deployed for longwave infrared methane detection, spectral features of methane are significantly interfered by water vapor variations at the edge of atmospheric window, which compromises detection performance. To address the spectral fitting degradation caused by relative changes between methane and water vapor signals, this study incorporates temperature, relative humidity, and sensing distance into the cost function, establishing a continuous optimization space with concentration path lengths (CLs) as variables, which are the product of the concentration and path length. A hybrid differential evolution and Levenberg–Marquardt (D-LM) algorithm is developed to enhance parameter estimation accuracy. Combined with a three-layer atmospheric model for real-time reference spectrum generation, the algorithm identifies the optimal spectral combination that provides the best match to the measured data. Algorithm performance is validated through two experimental configurations: Firstly, adaptive detection using synthetic spectra covering various humidity–methane concentration combinations is conducted; simulation results demonstrate that the proposed method significantly reduces the mean squared error (MSE) of fitting residuals by 95.8% compared to the traditional LASSO method, effectively enhancing methane spectral feature extraction under high-water-vapor conditions. Then, a continuous monitoring of controlled methane releases over a 500 m open path under high-outdoor-humidity conditions is carried out to validate outdoor performance of the proposed algorithm; field measurement analysis further confirms the method’s robustness, achieving a reduction in fitting residuals of approximately 57% and improving spectral structure fitting. The proposed approach provides a reliable technical pathway for adaptive gas cloud detection under complex atmospheric conditions.