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Copper-catalyzed hydroboration creates chiral allylboronates from cyclic dienes, suggesting new synthesis methods.
A copper‐catalyzed enantioselective hydroboration of cyclic dienes, which afford enantioenriched allylboronates, is disclosed. This reaction is catalyzed by a chiral bisphosphine–Cu complex in combination with commercially available pinacolborane as the hydroborane source. The method is applicable to 1‐aryl‐cyclohexadienes and 1,2‐dihydropyridine derivatives, affording allylboronate products in high regio‐ and enantioselectivity. The obtained allylboronates serve as versatile intermediates for the synthesis of diverse chiral compounds.
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You et al. (2026) studied this question.
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