Photoinduced Reversible Assembly of Polynuclear Complexes from Ru-Containing Ionic Liquids with Accompanying Ionic Conductivity Modulations

Key Points

• The central aim is to explore the photochemical reactivity of Ru-containing ionic liquids for assembling polynuclear complexes.
• Investigated photochemical reactivity of ionic liquids composed of Ru complexes.
• Evaluated the assembly process under light exposure.
• Assessed changes in ionic conductivity during the assembly.
• Successful reversible assembly of polynuclear complexes observed.
• Notable modulations in ionic conductivity linked to assembly process.
• Demonstrated solvent-free strategy for constructing coordination assemblies.