A New Polar Glass-Ceramic Built from Monovalent Perrhenate Anions and Large Methyltriphenylphosphonium Cations

Xiong Pan; Wei-Xiong Zhang; Zi-Luo Fang; Ming-Yu Guo; Hao Yang

doi:10.1039/d5cc07096a

January 1, 2026Chemical Communications

A New Polar Glass-Ceramic Built from Monovalent Perrhenate Anions and Large Methyltriphenylphosphonium Cations

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Key Points

The research aims to develop a new hybrid glass-ceramic material using specific anions and cations.
Constructed a hybrid compound using monovalent tetrahedral anions and bulky cations.
Characterized the compound's structure using polar space group Pca21.
Investigated reversible transitions between crystal and liquid states.
The new compound shows reversible crystal-liquid-glass-crystal transitions.
It exhibits a distinct polar nature due to its structural components.
The hybrid structure contributes to its unique physical properties.

Abstract

By employing monovalent and slightly-distorted tetrahedral[ReO₄]⁻ anions coupled with bulky methyltriphenylphosphonium cations (MTP + ), we constructed a new hybrid compuond in a polar space group Pca21. It exhibits reversible crystal-liquid-glasscrystal...

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Cite This Study

Pan et al. (2026) studied this question.

synapsesocial.com/papers/6975b229feba4585c2d6da5c https://doi.org/10.1039/d5cc07096a

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A New Polar Glass-Ceramic Built from Monovalent Perrhenate Anions and Large Methyltriphenylphosphonium Cations

Key Points

Abstract

Discussion

Cite This Study

A New Polar Glass-Ceramic Built from Monovalent Perrhenate Anions and Large Methyltriphenylphosphonium Cations

Key Points

Abstract

Discussion

Cite This Study

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