What question did this study set out to answer?

The research aims to develop a new hybrid glass-ceramic material using specific anions and cations.

January 25, 2026Chemical Communications0 citations

A New Polar Glass-Ceramic Built from Monovalent Perrhenate Anions and Large Methyltriphenylphosphonium Cations

XPXiong PanSun Yat-sen University WZWei-Xiong ZhangSun Yat-sen University ZFZi-Luo FangSun Yat-sen University

Key Points

The research aims to develop a new hybrid glass-ceramic material using specific anions and cations.
Constructed a hybrid compound using monovalent tetrahedral anions and bulky cations.
Characterized the compound's structure using polar space group Pca21.
Investigated reversible transitions between crystal and liquid states.
The new compound shows reversible crystal-liquid-glass-crystal transitions.
It exhibits a distinct polar nature due to its structural components.
The hybrid structure contributes to its unique physical properties.

Abstract

By employing monovalent and slightly-distorted tetrahedralReO₄⁻ anions coupled with bulky methyltriphenylphosphonium cations (MTP + ), we constructed a new hybrid compuond in a polar space group Pca21. It exhibits reversible crystal-liquid-glasscrystal...

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