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February 5, 2026Chemical Science1 citationsOpen Access

Pd-Catalyzed Stereospecific Synthesis of Reversed C-Acyl Glycosides: Access to Rare L-Sugars and Higher-Carbon Sugars

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GCGuoqiang ChengBYBo YangFZFeng Zhu

Key Points

  • This research aims to develop a method for synthesizing reversed C-acyl glycosides, particularly L-sugars and higher-carbon sugars.
  • Utilized palladium (Pd) catalysis for the synthesis process
  • Focused on stereospecific reactions to create nonclassical glycosides
  • Emphasized the versatility of the glycosides in potential applications
  • Successfully synthesized reversed C-acyl glycosides
  • Demonstrated the feasibility of producing L-sugars and higher-carbon sugars
  • Highlighted potential uses in medicinal chemistry

Abstract

Reversed C-acyl glycosides represent a versatile class of nonclassical glycosides with potential in complex carbohydrate synthesis, including L-sugars, higher-carbon sugars, and medicinal chemistry. Conventional strategies for L- and higher-carbon sugars...

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Cite This Study

Cheng et al. (2026) studied this question.

synapsesocial.com/papers/69843371f1d9ada3c1fb09e1https://doi.org/10.1039/d5sc08224b
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