From Centrosymmetric (C4H8N5)(SbF4) to Polar (C4H7N4O)(SbF4): A New UV Nonlinear Optical Material Achieved by Functional Group Modulation

Zhixiang Wang; Chun-Li Hu; Chuan‐Fu Sun; J. G. Mao; Fang Kong

doi:10.1039/d5sc09256f

January 1, 2026Chemical ScienceOpen Access

From Centrosymmetric (C4H8N5)(SbF4) to Polar (C4H7N4O)(SbF4): A New UV Nonlinear Optical Material Achieved by Functional Group Modulation

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Key Points

The research aims to design and synthesize new ultraviolet nonlinear optical materials with improved efficiency.
Employs functional group modulation strategy to alter material properties.
Synthesizes two specific compounds: centrosymmetric (C4H8N5)(SbF4) and polar (C4H7N4O)(SbF4).
Analyzes the relationship between nonlinear optical efficiency and optical bandgap.
Achieves a transition from centrosymmetric to polar structure, enhancing NLO properties.
Demonstrates improved NLO efficiency linked with optimized optical bandgap.

Implication

Research demonstrates enhanced NLO efficiency in ultraviolet materials, highlighting functional group modulation's importance.

Abstract

The design and synthesis of new ultraviolet nonlinear optical (NLO) materials is challenging due to the constraint relationship between their NLO efficiency and optical bandgap. By functional group modulation strategy,...

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Cite This Study

Wang et al. (2026) studied this question.

synapsesocial.com/papers/698433e9f1d9ada3c1fb16b7 https://doi.org/10.1039/d5sc09256f

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From Centrosymmetric (C4H8N5)(SbF4) to Polar (C4H7N4O)(SbF4): A New UV Nonlinear Optical Material Achieved by Functional Group Modulation

Key Points

Implication

Abstract

Discussion

Cite This Study

From Centrosymmetric (C4H8N5)(SbF4) to Polar (C4H7N4O)(SbF4): A New UV Nonlinear Optical Material Achieved by Functional Group Modulation

Key Points

Implication

Abstract

Discussion

Cite This Study

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