Ferrocene-containing Schiff bases and their Sn(IV) complexes with two non-conjugated redox-active fragments: dependence of spectroscopic and redox properties on complexation and solvent

Varvara Yu. Proshutinskaya; I. V. Krylova; Pavel G. Shangin; Victoriya A. Balycheva; Mikhail Evgenevich Minyaev; Dmitry E. Gorbunov; Nina P. Gritsan; Elena N. Nikolaevskaya; Mikhail P. Egorov; Evgeny V. Tretyakov; Mikhail A. Syroeshkin

doi:10.1039/d5nj04462f

January 1, 2026New Journal of Chemistry

Ferrocene-containing Schiff bases and their Sn(IV) complexes with two non-conjugated redox-active fragments: dependence of spectroscopic and redox properties on complexation and solvent

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Key Points

The aim is to explore how complexation and solvent affect the spectroscopic and redox properties of ferrocene-containing Schiff bases and their tin(IV) complexes.
Synthesis of ligands and tin(IV) complexes
Characterization through spectroscopic techniques
X-ray diffraction analysis for structural confirmation
Identified changes in redox properties upon complexation
Characterized unique spectroscopic signatures for complexes
Diverse behavior observed in different solvents

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Implication

Demonstrates the influence of complexation on redox properties in ferrocene-based ligands, indicating new insights into their applications.

Abstract

In this study, ligands and tin(IV) complexes containing two non‑conjugated redox‑active fragments – a Schiff base and an imino‑substituted ferrocene—were synthesized and characterized, including by X‑ray diffraction analysis. Complexation with...

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Proshutinskaya et al. (2026) studied this question.

synapsesocial.com/papers/69843405f1d9ada3c1fb1bb9 https://doi.org/10.1039/d5nj04462f

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Ferrocene-containing Schiff bases and their Sn(IV) complexes with two non-conjugated redox-active fragments: dependence of spectroscopic and redox properties on complexation and solvent

Key Points

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Implication

Abstract

Discussion

Cite This Study

Ferrocene-containing Schiff bases and their Sn(IV) complexes with two non-conjugated redox-active fragments: dependence of spectroscopic and redox properties on complexation and solvent

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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