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February 5, 2026Nanoscale2 citations

From chain to framework: atomically precise silver cluster-assembled architectures

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XLXiaolin LiuShandong University of Technology TKTaeyoung KiSeoul National University SYSeungwoo YooSeoul National University

Key Points

The research aims to investigate how ligand-directed assembly affects the formation and performance of silver nanocluster architectures.
Utilized ligand-directed assembly to construct 1D and 3D frameworks from Ag 12 nanoclusters.
Analyzed the structural integrity of the frameworks obtained after assembly.
Evaluated catalytic performance in nitroaromatic hydrogenation reactions.
1D framework exhibited superior catalytic performance compared to the 3D framework.
Structures were preserved during the assembly process, supporting efficiency in diverse applications.

Abstract

This study reveals that ligand-directed assembly enables Ag 12 nanoclusters to form 1D–3D frameworks with preserved structures, where the 1D framework shows the best catalytic performance in nitroaromatic hydrogenation.

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From chain to framework: atomically precise silver cluster-assembled architectures | Synapse

Cite This Study

Liu et al. (Thu,) studied this question.

synapsesocial.com/papers/6984347ff1d9ada3c1fb29a8 https://doi.org/https://doi.org/10.1039/d5nr04708k