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February 8, 2026Journal of Computational Biophysics and Chemistry0 citations

A new 1,8-naphthyridine-pivalamide hybrid: Synthesis, Structural elucidation, Hirshfeld surface analysis, DFT study, ADME analysis, and Molecular docking studies against EGFR and CDK6

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ISIndrajit SahaTSTanushree SenNBNabajyoti Baildya

Key Points

  • This research aims to synthesize and analyze a 1,8-naphthyridine-pivalamide hybrid for its binding properties against EGFR and CDK6.
  • Synthesis of the 1,8-naphthyridine-pivalamide hybrid
  • Characterization using FT-IR, NMR, X-ray analysis
  • Hirshfeld surface analysis for non-covalent interactions
  • DFT calculations for geometric optimization
  • Molecular docking studies to assess binding affinity with EGFR and CDK6
  • The compound demonstrated strong binding affinity with EGFR and CDK6 compared to known inhibitors.
  • Hirshfeld analysis revealed various non-covalent interactions supporting molecular stability.
  • Drug-likeness was confirmed via SwissADME predictions.

Abstract

This investigation focuses on the design, synthesis, comprehensive analysis, and binding affinity with the epidermal growth factor receptor (EGFR), Cyclin-Dependent Kinase 6 (CDK6) of a new 1,8-naphthyridine-pivalamide hybrid 1. The newly synthesised 1,8-naphthyridine-pivalamide hybrid 1 was characterised by FT-IR, 1 H NMR, elemental analysis, and single-crystal X-ray analysis. The crystal structure analysis disclosed that 1 is hydrated and supramolecular assembly is stabilized via O-H⋯N, N-H⋯O, and O-H⋯O and off-set 𝜋⋯𝜋 contacts. Various types of non-covalent contacts existing in the 1,8-naphthyridine-pivalamide hybrid 1 is explored, and subsequently quantified employing Hirshfeld surface analysis and 2D fingerprint plots. Furthermore, void study was utilised to examine the mechanical stability and presence of the cavity within the solid-state structure of 1. The interaction energies between molecules in 1 have been investigated using the interaction energy calculation. Geometric parameters of the optimized structure of 1 was determined utilizing the DFT calculations. Furthermore, molecular docking studies indicated that the 1,8-naphthyridine-pivalamide hybrid 1 demonstrated promising binding affinity with EGFR and CDK6, compared to their known inhibitors. The newly synthesized 1,8-naphthyridine-pivalamide hybrid 1 also exhibited drug-likeness as predicted by SwissADME.

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Cite This Study

Saha et al. (2026) studied this question.

synapsesocial.com/papers/6988277b0fc35cd7a8846435https://doi.org/10.1142/s2737416526500614
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