REV ₃ (BO ₃ ) ₄ (RE = La‒Nd): A Series of Rare Earth Vanadoborates Exhibit Large Birefringence Induced by Distorted V Ⅲ O ₆ Group

Yu-Long Wei; Wen-Dong Yao; Yi‐Lei Lv; Liang Ma; Ru-Ling Tang

doi:10.1039/d6cc00362a

January 1, 2026Chemical Communications

REV ₃ (BO ₃ ) ₄ (RE = La‒Nd): A Series of Rare Earth Vanadoborates Exhibit Large Birefringence Induced by Distorted V Ⅲ O ₆ Group

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Key Points

This research aims to synthesize and analyze the properties of new rare-earth vanadoborates.
Synthesized REV 3 (BO 3 ) 4 via high-temperature solid-state methods.
Determined the crystallization in a monoclinic system.
Conducted magnetic studies to assess antiferromagnetic behavior.
The synthesized compounds exhibit significant birefringence.
Antiferromagnetic behavior was successfully observed in the samples.
A unique {[V 3 O 14 ] 19- } ∞ chain structure was identified.

Implication

New vanadoborates demonstrate significant birefringence and antiferromagnetic behavior, indicating unique properties.

Abstract

New Rare-earth (RE) vanadoborates REV 3 (BO 3 ) 4 were synthesized via hightemperature solidstate methods. They crystallize in a monoclinic system featuring a unique {[V 3 O 14 ] 19- } ∞ chain. Magnetic studies reveal antiferromagnetic behavior, while...

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Cite This Study

Wei et al. (2026) studied this question.

synapsesocial.com/papers/6988278b0fc35cd7a8846632 https://doi.org/10.1039/d6cc00362a

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REV ₃ (BO ₃ ) ₄ (RE = La‒Nd): A Series of Rare Earth Vanadoborates Exhibit Large Birefringence Induced by Distorted V Ⅲ O ₆ Group

Key Points

Implication

Abstract

Discussion

Cite This Study

REV ₃ (BO ₃ ) ₄ (RE = La‒Nd): A Series of Rare Earth Vanadoborates Exhibit Large Birefringence Induced by Distorted V Ⅲ O ₆ Group

Key Points

Implication

Abstract

Discussion

Cite This Study

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