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February 8, 2026Environmental Science & Technology2 citations

Method Development and Sensitivity Optimization Paradigm for One-Step RPA-CRISPR/Cas12a Rapid Detection of the Hard-to-Amplify Gene bla NDM

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LSLingtao SunZLZishu LiuCDChifei Dong

Key Points

  • The aim is to develop a sensitive and rapid detection method for the blaNDM gene using RPA and CRISPR/Cas12a.
  • Utilized a one-step assay integrating RPA with CRISPR/Cas12a to target blaNDM.
  • Employed the MOSAIC paradigm for sensitivity optimization with multiple strategies.
  • Tested detection limits and accuracy using clinical and environmental samples.
  • Achieved a limit of detection of 260 copies/μL, similar to qPCR.
  • Demonstrated 100% diagnostic sensitivity and 95.45% specificity in clinical isolates.
  • Showed 77.41-99.73% accuracy in spiked environmental samples.

Abstract

The presence and spread of antibiotic resistance genes (ARGs) across various habitats have increased the risks of antibiotic resistance, highlighting the urgent need for effective monitoring methods. One key challenge in method development lies in balancing sensitivity, speed, and portability. To address it, a one-step assay targeting the carbapenem resistance gene blaNDM was developed based on recombinase polymerase amplification (RPA) combined with CRISPR/Cas12a. A sensitivity optimization paradigm─MOSAIC (multistrategy optimized sensitive assay via integrated CRISPR/Cas12a)─was proposed, incorporating component optimization, suboptimal-PAM-mediated CRISPR inhibition, and glycerol-assisted phase separation. The glycerol-assisted strategy exhibited the largest enhancement, followed by the suboptimal-PAM strategy and component optimization. When combined, these strategies demonstrated a synergistic effect, yielding greater improvement (10 000-fold) than a single strategy alone. MOSAIC reached a limit of detection (LOD) of 260 copies/μL, comparable to that of qPCR, and enabled faster quantification of blaNDM at 37 °C within 1 h on a standard plate reader. It achieved 100% diagnostic sensitivity and 95.45% specificity in clinical isolates, and 77.41-99.73% accuracy in environmental matrix-spiked samples, comparable to that of qPCR. It provides a technological foundation for on-site detection of blaNDM and offers an optimization paradigm and new insights for the development of one-step RPA-CRISPR/Cas12a assays targeting various genes.

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Cite This Study

Sun et al. (2026) studied this question.

synapsesocial.com/papers/6988278b0fc35cd7a8846688https://doi.org/10.1021/acs.est.5c10280
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