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February 9, 2026Water Air & Soil Pollution1 citationsOpen Access

Valorization of Turkish Coffee Waste in Chitosan-Based Biocomposites for Sr(II) Removal from Mixed-Ion Solutions: Optimization via Experimental Design

SBS. L. Hamarat BaysalSİSüleyman İnanBÖBekir Özkan

Key Points

  • To investigate the use of Turkish coffee waste in creating chitosan-based biocomposites for strontium ion (Sr(II)) removal from solutions.
  • Developed chitosan/TCW biocomposite beads for Sr(II) removal
  • Characterized the biocomposite using FTIR, BET, SEM, and pH pzc analyses
  • Examined effects of various parameters on Sr(II) sorption using a Central Composite Design (CCD)
  • Employed statistical methods including ANOVA and isotherm models for data analysis
  • Biocomposite exhibited a maximum adsorption capacity of 17.20 mg g –1 for Sr(II)
  • The adsorption kinetics were best described by a pseudo-second-order model
  • Isotherm data fit well with the D–R model, showing a high determination coefficient (R² = 0.999)
  • Competitive cations significantly reduced Sr(II) uptake
  • Adsorption process was found to be spontaneous and exothermic, improving slightly with temperature increase.

Abstract

Abstract Turkish coffee is a widely consumed coffee type, generating large amounts of waste daily. Recycling coffee waste plays a crucial role in mitigating potential environmental risks. In this regard, we propose a study to explore the reuse of Turkish coffee waste (TCW) by incorporating it into a chitosan solution to create novel chitosan/TCW biocomposite beads. The prepared chitosan/TCW biocomposite was characterized through FTIR, BET surface area, SEM, and pH pzc analyses. The impact of various parameters, such as initial pH, contact time, Sr(II) concentration, and temperature, on Sr(II) sorption was examined using a 4-factor, 5-level Central Composite Design (CCD). The analysis of variance (ANOVA) results showed that the Model F -value of 97.32 indicates the model's significance. The coefficient of determination ( R 2 ) between the experimental and predicted results was 0.989. The adsorption data were best described by the D–R isotherm, which exhibited the highest determination coefficient ( R 2 = 0.999) and the lowest prediction errors, indicating superior agreement with experimental values. The biocomposite's maximum adsorption capacity was determined to be 17.20 mg g –1 . The kinetics of Sr(II) adsorption are well described by the pseudo-second-order kinetic model. Adsorption process is spontaneous, exothermic, and becomes slightly more favorable with increasing temperature. Competitive ion studies further revealed that the presence of competing cations significantly reduced Sr(II) uptake. Overall, the results demonstrated that the chitosan/TCW biocomposite can be effectively used for removing strontium from a wide range of aqueous solutions.

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Cite This Study

Baysal et al. (2026) studied this question.

synapsesocial.com/papers/69897a86f0ec2af6756e8ae0https://doi.org/10.1007/s11270-026-09218-5
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