Shows the reduction of electrical charging in insulators using heating during photoelectron spectroscopy, suggesting effective techniques for material analysis.
The electrical charging of insulating samples is a common problem in photoelectron spectroscopy. Although heating has been suggested as a way to minimize surface charging, systematic studies of this are scarce. We have found that during 8 keV photoelectron spectroscopy using a synchrotron, the extent of charging of three highly insulating materials could be significantly reduced with increasing temperature. The charging of glass and LiNbO3 samples could be almost completely compensated at a moderate temperature of ∼400 °C. Based on the temperature dependence of charging-induced binding energy shift, the activation energies of the charge compensation were evaluated to be about 0.73, 0.65, and 0.21 eV for a glass slide, cover glass, and LiNbO3, respectively. Furthermore, charge compensation was achieved by surface conduction rather than bulk conduction.
No takes yet. Share an insight, caveat, or question.
Fujiki et al. (2026) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: