What question did this study set out to answer?

The aim is to improve CO2 photocatalytic reduction performance in MOF-545 by modifying linker structures.

February 12, 2026Dalton Transactions0 citations

Tailoring porphyrinic MOF-545 performances for CO 2 photocatalytic reduction through linker chlorination

ARA. D. RobinsonCentre National de la Recherche Scientifique SSSadiya SadiyaCentre National de la Recherche Scientifique SKSandeep KumarCentre National de la Recherche Scientifique

Key Points

The aim is to improve CO2 photocatalytic reduction performance in MOF-545 by modifying linker structures.
Chlorination of porphyrin linkers in MOF-545
Assessment of photocatalytic CO2 conversion under visible light
Evaluation of changes in electronic structure and band gap
Increased photocatalytic conversion of CO2 to formate
Enhanced efficiency attributed to altered electronic structure
Optimized band gap for better light absorption

Abstract

Chlorinating porphyrin linkers in MOF-545 boosts photocatalytic CO 2 -to-formate conversion under visible light by tuning the electronic structure and the band gap.

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