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February 12, 2026The Journal of Chemical Physics0 citations

Dipolar cohesion in densely packed confined columns

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DYDuan YanYuZGZecheng GanHBH. Boumrar.

Key Points

  • This research investigates how the dipolar cohesion of magnetic sphere assemblies changes based on cylinder diameter.
  • Theoretical analysis using exact geometrical solutions.
  • Application of dipolar lattice sums to assess cohesive energy.
  • Examination of zigzag and helical regimes in confined structures.
  • Cohesive energy shows nonmonotonic behavior due to competing pressures.
  • A critical point exists where cohesion is weakest, followed by structural stabilization.
  • Larger diameters exhibit similar behavior with quasi-degeneracy between two morphologies.

Abstract

We investigate theoretically the dipolar cohesion of densely packed columnar assemblies of identical magnetic spheres confined in a cylinder, whose dipole moments are aligned by a tunable strong external magnetic field. Using exact geometrical solutions and dipolar lattice sums, we analyze how the cohesive energy depends on the cylinder diameter. In the zigzag regime, the cohesion exhibits a pronounced nonmonotonic behavior that can be rationalized in terms of competing radial and longitudinal pressures arising from a breaking of ideal head-to-tail dipolar alignment. This competition leads to a point of weakest cohesion, followed by a stabilization of the densest zigzag structure driven by long-range interchain correlations. At larger diameters, a similar bell-shaped evolution of the cohesive energy is found in the helical regime, together with a striking quasi-degeneracy between zigzag and helical morphologies. Our results are directly relevant to experiments on confined dipolar soft matter, ranging from field-responsive magnetic colloids to paramagnetic granular media.

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Cite This Study

YanYu et al. (2026) studied this question.

synapsesocial.com/papers/698d6eca5be6419ac0d54902https://doi.org/10.1063/5.0320145
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