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February 12, 2026Gels4 citationsOpen Access

CNF/p(AM-co-KAA) Semi-Interpenetrating Network Hydrogel Fertilizer Carriers for Enhanced Nutrient Use Efficiency, Water Retention, and Salt–Alkali Resistance

JPJingxuan PanYWY. WangJWJingwei Wang

Key Points

  • This research aims to develop a multifunctional hydrogel that enhances nutrient release, water retention, and soil amendment.
  • Synthesis of CPAUH hydrogel using a one-pot strategy
  • Characterization through FTIR, TGA, SEM, and XPS
  • Evaluation of nutrient release kinetics over 15 days
  • Assessment of wheat growth under salt stress compared with control
  • CPAUH exhibited high mechanical strength (0.169 MPa) and water absorption capacity (121.65 g g−1)
  • Sustained-release behavior with 66.91% urea and 92.45% humic acid over 15 days
  • Increased wheat growth with significant improvements in height and nitrogen uptake under salt stress
  • Reduced soil electrical conductivity by 39.16% after amendment

Abstract

Developing functional agricultural materials that synchronize nutrient release, water retention, and soil amendment is crucial to advancing resource-efficient, sustainable farming systems. However, integrating these multifunctional properties within a single material remains a significant challenge. In this work, we fabricated a multifunctional hydrogel (CPAUH) via a one-pot synthesis strategy, which was composed of carboxylated cellulose nanofibers as a rigid network combined with poly(AA-co-KAA), forming a semi-interpenetrating network (semi-IPN) for loading urea and humic acid. The structure and properties of hydrogels were characterized by FTIR, TGA, SEM, and XPS. The CPAUH exhibited outstanding mechanical strength (0.169 MPa), water absorption capacity (121.65 g g−1), and retained 118 g g−1 after three absorption–desorption cycles, demonstrating remarkable structural stability. Nutrient release kinetics revealed sustained-release behavior, with cumulative elution of only 66.91% for urea and 92.45% for humic acid over 15 days. Under salt stress, the 1.5% CPAUH amendment (P2) markedly enhanced wheat growth compared with the non-amended control (P0), as reflected by significant increases in plant height, chlorophyll content, fresh weight, dry weight, and nitrogen uptake. Concurrently, CPAUH application effectively improved soil conditions by reducing electrical conductivity by 39.16% (to 4.38 mS·cm−1). These collective findings of CPAUH hydrogel offer substantial potential as a multifunctional soil amendment for enhancing water-fertilizer efficiency, reclaiming saline–alkali soils, and improving crop productivity under resource-limited conditions.

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Cite This Study

Pan et al. (2026) studied this question.

synapsesocial.com/papers/698d6edc5be6419ac0d54bb4https://doi.org/10.3390/gels12020157
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