Reductive hydroformylation of methyl 10-undecenoate catalyzed by a rhodium/trialkylamine combination associated with silica: A new step towards a simple, robust and recyclable catalytic system

Abdelhadi Zouhair; Michel Ferreira; Hervé Bricout; Nicolas Kania; Bastien Léger; Jérémy Ternel; Anne Ponchel; Mohammed Lahcini; Sebastien Tilloy; Eric Monflier

doi:10.1039/d5cy01529d

January 1, 2026Catalysis Science & Technology

Reductive hydroformylation of methyl 10-undecenoate catalyzed by a rhodium/trialkylamine combination associated with silica: A new step towards a simple, robust and recyclable catalytic system

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Key Points

The aim is to explore the efficacy of a rhodium/trialkylamine system for the reductive hydroformylation of methyl 10-undecenoate, leveraging silica for immobilization.
Conducted reductive hydroformylation reactions using rhodium and trialkylamine with silica support.
Assessed the catalytic performance and immobilization efficiency of the catalytic system.
Compared the new catalytic system's effectiveness to existing methods.
Achieved over 95% immobilization of the rhodium/amine catalyst with silica support.
Demonstrated improved catalytic efficiency in the hydroformylation process.
Highlighted the recyclability of the new catalytic system for future applications.

Implication

Experimental investigation demonstrates a novel catalytic system for hydroformylation, suggesting enhanced efficiency and recyclability.

Abstract

The reductive hydroformylation of methyl 10-undecenoate catalysed by a rhodium/amine system was investigated in the presence of silica. The addition of silica enabled the immobilisation of over 95% of the...

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Cite This Study

Zouhair et al. (2026) studied this question.

synapsesocial.com/papers/698d6eeb5be6419ac0d54e8d https://doi.org/10.1039/d5cy01529d

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Reductive hydroformylation of methyl 10-undecenoate catalyzed by a rhodium/trialkylamine combination associated with silica: A new step towards a simple, robust and recyclable catalytic system

Key Points

Implication

Abstract

Discussion

Cite This Study

Reductive hydroformylation of methyl 10-undecenoate catalyzed by a rhodium/trialkylamine combination associated with silica: A new step towards a simple, robust and recyclable catalytic system

Key Points

Implication

Abstract

Discussion

Cite This Study

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