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Catalytic hydroboration shows selective formation of alkyl boronic esters in unactivated alkenes, suggesting new synthetic pathways.
Catalytic Markovnikov-selective hydroboration of unactivated alkenes is a powerful tool for accessing alkyl boronic esters. Here, we report Markovnikov-selective MHAT hydroboration of unactivated alkenes enabled by cobalt/photoredox dual catalysis. The reaction proceeded via radical intermediates, providing high regioselectivity with mono-, di-, and trisubstituted alkenes.
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Seino et al. (2026) studied this question.
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