This study presents a comparative analysis of cylindrical lithium-ion cell architectures, tracing the evolution from the conventional tabbed design (18650/21700) to the large-format 4680 cell with its tabless current collectors. This architectural shift is driven by the imperative to minimise internal ohmic resistance and enhance thermal management in high-power automotive battery applications. Forensic investigation reveals that the 4680 design replaces localised, high-resistance tab connections with a distributed, low-impedance interface, necessitating the adoption of advanced manufacturing techniques, including long ultrasonic torsional welding and highly controlled high-power density laser welding. Crucially, the welding of external aluminium busbars to the cell relies on sophisticated microstructural engineering, particularly for the challenging dissimilar Aluminium-Steel (Al-Steel) anode weld. This weld format employs a spiral laser path to limit the formation of brittle aluminium-iron (Al-Fe) intermetallic compounds (IMCs), leveraging the steel cell casing’s nickel plating to promote a more ductile Al-Fe-Ni phase for improved joint reliability. Furthermore, the 4680 cell incorporates a significantly thicker casing (≈0.54 to 0.7 mm) for enhanced mechanical strength. In conclusion, the 4680 cell achieves superior performance through robust mechanical design and advanced welding processes that prioritise microstructurally sound, low-resistance interfaces.
Asirvatham et al. (2026) studied this question.