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February 21, 2026Journal of Chemical Education4 citations

Green Synthesis of Fe 3 O 4 Nanozyme with Peroxidase-like Activity for Colorimetric Glucose Detection: A Comprehensive Undergraduate Laboratory Experiment

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JDJiaojiao DuFLFen LiYFYing Fang

Key Points

  • The study aims to develop an eco-friendly method for synthesizing iron oxide nanozymes for glucose detection in educational settings.
  • Synthesis of iron oxide nanozymes using lemon peel extract as a reducing agent.
  • Characterization of nanozymes through SEM, XRD, XPS, and FT-IR techniques.
  • Evaluation of peroxidase-like activity with a chromogenic substrate and H2O2.
  • Implementation of a colorimetric glucose detection method utilizing nanozyme-glucose oxidase cascade.
  • Iron oxide nanozymes exhibited significant peroxidase-like activity.
  • Positive feedback from students indicated improved understanding of green chemistry and catalytic mechanisms.
  • The experiment proved adaptable to various educational settings and disciplines.

Abstract

Nanomaterial-based enzyme mimics, known as nanozymes, are extensively applied in chemical sensing and biomedical fields due to their low cost, high stability, and tunable catalytic activity. However, conventional synthesis methods employing hazardous chemicals limit their promotion in undergraduate laboratory training. Herein, an eco-friendly and simple green approach is proposed that utilizes plant extracts as natural reducing agents for nanozyme synthesis. Iron oxide nanozymes (Fe3O4 NZs) were synthesized using lemon peel extract, and their structures and properties were analyzed via SEM, XRD, XPS, and FT-IR. The peroxidase-like activity of Fe3O4 NZs was evaluated using a chromogenic substrate in the presence of H2O2. Additionally, their effectiveness in developing nanozyme-glucose oxidase (GOx) cascade colorimetric sensors for glucose detection was also demonstrated. These experiments have been successfully conducted at various undergraduate levels and have received positive feedback. Experimental assessments indicated that students’ understanding of green chemistry, catalytic mechanisms, and interdisciplinary applications of nanozymes had improved. Moreover, the flexible design of the experiment allows instructors to modify it based on students’ backgrounds, available equipment, and teaching objectives, making it applicable to multiple fields such as chemistry, materials science, and biology. This experiment provides a generalizable case for integrating cutting-edge technology into undergraduate education.

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Cite This Study

Du et al. (2026) studied this question.

synapsesocial.com/papers/69994b64873532290d01f8bdhttps://doi.org/10.1021/acs.jchemed.5c00774
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