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February 21, 2026Industrial & Engineering Chemistry Research2 citations

Perspectives on the Essential Role of First-Principles Modeling in the Age of AI

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AKAnton A. KissJGJohan Grievink

Key Points

  • To evaluate the integration of first-principles modeling and AI in chemical engineering, focusing on their complementary roles.
  • Analyzed the evolution of AI, machine learning, and neural networks in modeling.
  • Discussed the benefits and limitations of data-driven and first-principles approaches.
  • Identified key decision points in the model-building workflow.
  • Explored case studies illustrating practical strategies for model integration.
  • Highlighted the indispensable role of first-principles modeling for safety and reliability.
  • Demonstrated the benefits of hybrid approaches combining FPM and AI.
  • Identified opportunities for improving model validation and scalability in industrial applications.

Abstract

The evolution of artificial intelligence (AI), machine learning (ML), and neural networks (NN) is transforming the landscape of scientific and engineering modeling. It also prompts a debate on the role of first-principles modeling (FPM) in chemical engineering. While data-driven methods excel at interpolation and very rapid development, they often lack physical fidelity, interpretability, and reliable extrapolation capabilities. This article provides a personal academic and industrial perspective on the synergistic integration of FPM and AI-based methods, highlighting their complementary roles in process systems engineering. We argue that FPM (based on fundamental conservation laws and mechanistic understanding of phenomena), remains indispensable for ensuring robustness, safety, physical consistency, and adaptability of models in PSE. Moreover, we analyze the synergistic potential of hybrid approaches by deconstructing the model-building workflow. The latter is the primary lens to identify key decision points where integration delivers maximum value, moving beyond a simple paradigm comparison. Using this structured analysis of the model-building workflow, we identify several major opportunities for this integration, particularly where first-principles knowledge is incomplete. The discussion extends to practical strategies for model validation, scalability, and industrial applications, supported by case studies, as well as the potential of LLMs in assisting the future developments of FPM. Finally, we conclude that a physics-informed foundation for modeling is not obsolete but is instead critical for guiding the safe and reliable application of AI in chemical engineering.

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Cite This Study

Kiss et al. (2026) studied this question.

synapsesocial.com/papers/69994c4b873532290d020a99https://doi.org/10.1021/acs.iecr.5c04156
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