Unraveling the Effects of Ion Exchange Membranes on the Performance of Real Wastewater Treatment in Microbial Fuel Cells

This study investigated the comparative performance of anion exchange membranes (AEMs), cation exchange membranes (CEMs), and bipolar membranes (BPMs) in dual-chamber microbial fuel cells (MFCs) operated under fed-batch real wastewater conditions. The experimental studies focused on electrical output; pH shifts; and changes in chemical oxygen demand (COD), total nitrogen, total phosphorus, and ammonia concentrations. The results revealed distinct performance profiles for each membrane type. The CEM system supported high removal of COD, TN, and ammonia (≈75–85% ± 2%). In contrast, the AEM achieved excellent phosphorus removal (≈95% ± 2%) alongside strong COD reduction, although nitrogen and ammonia removal were comparatively lower. BPM systems exhibited lower COD removal (typically <65%) but achieved moderate and stable reductions in TN, ammonia, and phosphorus while producing electrical output consistently higher than AEMs and at intermediate levels relative to CEMs. Quantitative analysis of power generation further confirmed this trend, with CEM delivering the highest output (8.93 mW/m2), BPM providing moderate performance (3.38 mW/m2), and AEM producing the lowest (1.5 mW/m2). The results emphasize that membranes influence the balance between nutrient removal and energy recovery and that aligning membrane selection with specific treatment objectives may advance MFCs from laboratory demonstrations toward practical applications.