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February 23, 2026Crystal Growth & Design2 citationsOpen Access

A Versatile Synthesis Approach and Interface Characterization of t-ZnO@Metal Hydroxide/Oxide Heterostructures

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BCBarnika ChakrabortyTTTim TjardtsBZBerit Zeller-Plumhoff

Key Points

  • The research aims to explore the synthesis of t-ZnO@metal hydroxide/oxide heterostructures and their properties.
  • Utilized a wet chemical synthesis approach for generating core-shell structures.
  • Conducted structural and morphological characterization using techniques such as SEM and TEM.
  • Investigated interfaces using XPS, XRD, and Raman spectroscopy.
  • Achieved uniform coating of t-ZnO with metal hydroxides, forming platelets.
  • Highlighted the unique structural advantages of t-ZnO for synthesizing various metal oxides and hydroxides.

Abstract

Functional ceramics play a key role in technology, particularly in piezoelectric sensors and actuators, ferroelectric power generation, and durable semiconductors used in sensors and memristors. In this study, we report a versatile wet chemical synthesis approach, converting the surface of functional tetrapodal zinc oxide (t-ZnO) to common metal hydroxides. We performed structural, morphological, and interface characterization and explored the subsequent application of various t-ZnO@metal hydroxide/oxide core–shell structures. The t-ZnO core was initially uniformly coated with different metal hydroxides, forming distinct platelets in a core–shell architecture. Interface studies were conducted to investigate the chemical, structural, and morphological properties of these hybrid microstructures using 2D scanning nano X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), bulk XRD, X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. Our findings highlight the potential of exceptional t-ZnO structures as versatile templates, offering their morphology for the synthesis of derived oxides and hydroxides of many other elements while leveraging their structural advantages.

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Cite This Study

Chakraborty et al. (2026) studied this question.

synapsesocial.com/papers/699bee551c6c6bad5397ff04https://doi.org/10.1021/acs.cgd.5c01604
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