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February 25, 2026Journal of Applied Physics0 citationsOpen Access

Measurements of the inert Hugoniot and observation of mechanical ignition in Ni(V) + Al reactive multilayers via x-ray diffraction

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MKMelia KendallPSPaul SpechtCMChad McCoy

Key Points

  • This research examines the inert Hugoniot response and mechanical ignition of Ni(V)+Al multilayers under shock compression.
  • Conducted longitudinal, laser-driven shock compression experiments on Ni(V)+Al multilayers.
  • Utilized in situ x-ray diffraction (XRD) to analyze phase changes during compression.
  • Measured reaction dynamics and pressure responses exceeding 50 GPa using hydrocode simulations.
  • Confirmed that Ni(V) and Al were not in equilibrium during compression due to structural effects.
  • Observed reactions at higher stresses than previous reports, indicating altered thresholds due to shear stress.
  • Demonstrated complete melting of the multilayer within 40 ns after shock-wave passage.

Abstract

This study investigates the inert Hugoniot response, mechanical ignition, and reaction dynamics of Ni(V)+Al multilayers during longitudinal, laser-driven shock compression experiments. Ni(V)+Al multilayers, known for their self-propagating exothermic reactions, were subjected to longitudinal stresses exceeding 50 GPa using the laser shock facility within the Dynamic Compression Sector (DCS) at the Advanced Photon Source (APS). In situ x-ray diffraction (XRD) revealed that Ni(V) and Al were not in equilibrium during compression, with stress discrepancies attributed to twinning, grain structure effects, and/or dislocation density. However, the measured inert Hugoniot closely matched prior experimental and computational studies, confirming the utility of XRD for measuring the equation of state of thin, complex materials. Additionally, reaction was observed at significantly higher stresses than reported previously using laser-launched flyers. This discrepancy suggests a strong influence of externally imposed shear stress on reaction thresholds, which likely arose from deviations in flyer planarity during past experiments. Full reaction of the multilayer occurred within 40 ns after shock-wave passage, evidenced by complete melting of the constituents. Eulerian hydrocode simulations replicated experimental conditions, providing insights into equilibrium dynamics and experimental artifacts. The results highlight how even small shear forces facilitate ignition in Ni(V)+Al multilayers at lower stresses.

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Cite This Study

Kendall et al. (2026) studied this question.

synapsesocial.com/papers/699e919cf5123be5ed04f3f0https://doi.org/10.1063/5.0308428
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