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February 26, 2026Journal of Archaeological Science Reports0 citationsOpen Access

Monitoring mineralogical and porosity transformations in modern Hebron ceramics caused by salt whitening agent using non-invasive methods

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NCNadia CANTINLTLaura TeodorescuRLRonan Ledevin

Key Points

  • This research aims to investigate how salt affects the porosity and physical properties of ceramics valued by potters.
  • Conducted a field investigation among potters in Hebron to understand salt use in ceramics.
  • Produced test briquettes in the lab with controlled salt concentration and firing temperatures.
  • Employed hyperspectral imaging to estimate firing temperatures and X-ray micro-tomography to assess porosity.
  • Porosity increased with higher firing temperatures.
  • Addition of salt caused a redistribution of pores, favoring macropore formation.
  • Hyperspectral imaging proved effective for non-destructive estimation of firing temperatures.

Abstract

• Micro-CT highlights the effects of adding sodium chloride salt on ceramic porosity and the redistribution of pores. • SWIR Hyperspectral Imaging allows the observation of phase changes resulting from variations in ceramic firing temperatures. • SWIR Hyperspectral Imaging presents great potential for determining firing temperatures using non-destructive tools. A field investigation conducted among potters in Hebron (Palestinian Territories) revealed the use of salt in clay pastes to produce white ceramics. An initial study ( Teodorescu et al., 2022 ) sought to understand and explain this phenomenon. In addition to the visible whiteness, the potters also emphasised other qualities, such as porosity. This research aims to explore how the addition of salt influences the material’s properties to meet both the aesthetic and functional criteria valued by the potters. At the outset, raw materials and finished products were sampled directly from workshops in Hebron. A series of test briquettes were then produced in the laboratory following a protocol that allowed for precise control of both salt concentration and firing temperatures, based on the raw materials used by the Hebron potters. The goal was to assess the role of temperature and salt concentration in the development of the material’s pore structure. Firing temperatures were estimated from the reflectance spectral response obtained in the short-wave visible range (400–800 nm) and the infrared range (1000–2500 nm), using a hyperspectral camera (HSI). At the same time, the material’s porosity was examined through X-ray micro-tomography. The results indicated an increase in porosity with increasing temperature. More significantly, the addition of salt led to a redistribution of pores, favouring the formation of macropores. Furthermore, the results revealed that hyperspectral imaging is a highly promising non-destructive tool for estimating the firing temperature of ancient ceramics.

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Cite This Study

CANTIN et al. (2026) studied this question.

synapsesocial.com/papers/699fe28895ddcd3a253e6534https://doi.org/10.1016/j.jasrep.2026.105660
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