Copper(III) Trifluoromethyl Tris(pyrazolyl)borates

Q: What does this research mean for the field?

Copper(III) scorpionate complexes TpCu(CF3)2 and Tp*Cu(CF3)2 were successfully synthesized and characterized for the first time. Novelty: ClaimNovelty.NOVEL_FINDING. Consensus alignment: ConsensusAlignment.NEUTRAL.

Vladimir Motornov

doi:10.1039/d6qi00184j

January 1, 2026Inorganic Chemistry FrontiersOpen Access

Copper(III) Trifluoromethyl Tris(pyrazolyl)borates

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Key Points

The aim is to synthesize and characterize new copper(III) scorpionate complexes.
Synthesis of TpCu(CF3)2 and Tp*Cu(CF3)2 via ligand exchange reactions
Use of acetylacetonate complex for synthesis
Characterization of the complexes through structural analysis
Successful synthesis of high-valent copper(III) complexes
Full characterization confirmed their structure and expected oxidation state
Demonstration of effective ligand exchange in forming copper(III) complexes

Implication

Synthesizes and characterizes copper(III) complexes, suggesting new pathways in coordination chemistry.

Abstract

The first scorpionate complexes of high-valent copper(III) TpCu(CF3)2 and Tp*Cu(CF3)2 were synthesized by ligand exchange reaction in acetylacetonate complex (acac)Cu(CF3)2 and fully characterized. The structure, effective oxidation state of copper,...

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Cite This Study

Vladimir Motornov (2026) studied this question.

synapsesocial.com/papers/699fe3f995ddcd3a253e80ec https://doi.org/10.1039/d6qi00184j

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Copper(III) Trifluoromethyl Tris(pyrazolyl)borates

Key Points

Implication

Abstract

Discussion

Cite This Study

Copper(III) Trifluoromethyl Tris(pyrazolyl)borates

Key Points

Implication

Abstract

Discussion

Cite This Study

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