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March 1, 2026Discover Geoscience0 citationsOpen Access

Appraisal of sources, pollution and risks of some metals in soil and water using geochemical and multivariate statistical approach, eastern Niger Delta, Nigeria

EKEbenezer A. KudamnyaAEAniekan EdetBBBassey Okon Bassey

Key Points

  • To evaluate the sources and health risks of heavy metals in soil and water in the Niger Delta area.
  • Analyzed 54 soil and 42 water samples for physical and chemical parameters.
  • Utilized indexed and statistical techniques to assess contamination levels.
  • Conducted factor analysis to determine sources of metal contamination.
  • Calculated risk assessment through hazard quotient and hazard index.
  • Soil samples were found to be acidic with high electrical conductivity.
  • More than 50% of water samples showed contamination levels due to seawater.
  • Positive and negative correlations indicated different sources and common factors for metals.
  • Risk assessment revealed minimal risk from soil exposure but significant risk from water ingestion.

Abstract

The sources and contamination level including human health risks in soil, surface water and groundwater by some heavy metals in the Niger Delta area, Nigeria were investigated. Fifty-four soil and forty-two water samples were analyzed for physical and chemical parameters and heavy metals based on standard methods. Indexed and statistical techniques were applied in order to assess the extent of contamination from saltwater intrusion and metals. Results revealed that the soils were acidic with electrical conductivity > 40 mg/kg, suggesting effect of seawater. High concentration of some metals characterized soil. The ratios Na+/Cl−, Cl−/HCO3− and scatter plots of Cl− versus EC suggest contamination of the water by sea water. Different contamination indices indicate that more than 50% of the water samples were contaminated. Significant positive correlation suggests common sources, while significant negative correlation suggest a different sources for the metals. Factor analysis indicate that the metal contamination was due to different sources. Risk assessment through hazard quotient and hazard index via soil exposure pathway were 1, suggesting adverse noncarcinogenic health risk. The cancer risk level in water for Cd and Cr exceeded the recommended value, compared to soil. In conclusion, most of the water samples if consumed continuously may constitute health risk.

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Cite This Study

Kudamnya et al. (2026) studied this question.

synapsesocial.com/papers/69a3d811ec16d51705d2e8cfhttps://doi.org/10.1007/s44288-026-00443-3
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