Mild steel readily corrodes in acidic environments, and most industrial corrosion inhibitors are synthetic, often toxic, and environmentally harmful. In this study, electrocatalytically active Cd–Cs mixed oxide nanocomposites were synthesized via a green route using an aqueous extract of Trachyspermum ammi (ajwain) seeds as a natural reducing, stabilizing, and capping agent. This eco-friendly method eliminates harsh chemicals while producing nanomaterials with active surfaces capable of facilitating electron transfer and scavenging free radicals. Incorporation of cesium introduces basic, electron-rich sites on the Cd–Cs oxide surface, serving as inhibition promoters that enhance charge transfer at the metal/electrolyte interface and assist in the formation of an adsorbed protective film on steel. The nanocomposites were optimized by adjusting precursor ratios, pH, temperature, and reaction time, and were characterized by UV–Vis, FTIR, XRD, SEM–EDS, HR-TEM EDS, BET, DLS, XPS, and zeta potential analyses. Strong antioxidant activity in ABTS and DPPH assays confirmed efficient catalytic quenching of reactive radicals. Corrosion inhibition potential, evaluated by using potentiodynamic polarization, electrochemical impedance spectroscopy, and gravimetric analysis in 0.5 M HCl, shows an inhibition efficiency of 90–91%. This performance is associated with an electrocatalytically active, adsorbed barrier layer that suppresses both anodic dissolution and cathodic hydrogen evolution, which depicts mixed-type inhibition. Overall, the biosynthesized Cd–Cs mixed oxide nanocomposites function as promising green synthesized nanomaterial with dual antioxidant and corrosion-inhibiting functions, underscoring their potential for advanced surface engineering and corrosion protection.
Naik et al. (Wed,) studied this question.