Pd@CN-COF: A Pool for Palladium(0)-Catalyzed Reactions

Key Points

• The aim is to develop a new cyano-substituted olefin-linked COF as a support for palladium nanoparticles to enhance catalytic efficiency.
• Synthesis of cyano-substituted olefin-linked COF as a support material.
• Incorporation of palladium nanoparticles onto the COF support.
• Evaluation of Pd@CN-COF's catalytic performance in cross-coupling reactions and cyanation.
• Pd@CN-COF exhibited high catalytic activity in multiple cross-coupling reactions.
• The catalyst showed efficiency in cyanation reactions producing desired products.
• Recyclability of Pd@CN-COF was demonstrated across several reaction cycles, maintaining activity.