Lighting Up Hypochlorous Acid through C(sp2)-H Hydroxylation with a Solvatochromic Organoiridium(III) Complex-based Probe

Q: What does this research mean for the field?

A solvatochromic Ir(III) complex enables the highly selective detection of hypochlorous acid (HOCl) through a C(sp2)-H hydroxylation mechanism. Novelty: ClaimNovelty.NOVEL_FINDING. Consensus alignment: ConsensusAlignment.NEUTRAL.

Snehadrinarayan Khatua; Bhaskar Sen; Jogat Gogoi; Kripamoy Aguan

doi:10.1039/d6an00002a

January 1, 2026The Analyst

Lighting Up Hypochlorous Acid through C(sp2)-H Hydroxylation with a Solvatochromic Organoiridium(III) Complex-based Probe

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Key Points

This research aims to achieve selective detection of hypochlorous acid using a specific organometallic complex.
Utilized a solvatochromic cyclometalated Ir(III) complex for detection.
Employed a unique mechanism for C(sp2)-H hydroxylation.
Conducted experiments to evaluate selectivity and sensitivity of the complex.
Demonstrated high selectivity for hypochlorous acid over other reactive species.
Achieved effective detection through C(sp2)-H hydroxylation mechanism.

Implication

Investigation reveals selective detection of hypochlorous acid using an organometallic probe, highlighting potential for diagnostic applications.

Abstract

Herein, we report the highly selective detection of the reactive oxygen species hypochlorous acid (HOCl) using a solvatochromic cyclometalated Ir(III) complex through a unique C(sp2)-H hydroxylation mechanism. The complex, Ir-1,...

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Cite This Study

Khatua et al. (2026) studied this question.

synapsesocial.com/papers/69a7cd2ad48f933b5eed94f4 https://doi.org/10.1039/d6an00002a

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Lighting Up Hypochlorous Acid through C(sp2)-H Hydroxylation with a Solvatochromic Organoiridium(III) Complex-based Probe

Key Points

Implication

Abstract

Discussion

Cite This Study

Lighting Up Hypochlorous Acid through C(sp2)-H Hydroxylation with a Solvatochromic Organoiridium(III) Complex-based Probe

Key Points

Implication

Abstract

Discussion

Cite This Study

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