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March 4, 2026Communications Engineering2 citationsOpen Access

X-ray fluorescence spectroscopy for rapid identification of cathode chemistry in lithium-ion battery recycling

FRFeihong RenVVVladimir VidalACAndréa Campos

Key Points

  • The aim is to develop a fast and effective method for classifying cathode chemistry in lithium-ion batteries to enhance recycling efforts.
  • Utilized X-ray fluorescence spectroscopy for non-destructive analysis
  • Established a reference dataset from over 100 used lithium-ion batteries
  • Employ statistical grouping for defining cathode categories
  • Validated results through selective disassembly and complementary chemical analysis
  • Applied a trained classification model for rapid identification of new battery spectra
  • Achieved high prediction accuracy for cathode classification
  • Enabled identification of battery chemistry within seconds
  • Reduced reliance on disassembly for analysis
  • Demonstrated feasibility for large-scale battery recycling applications

Abstract

Efficient identification of cathode chemistry in end-of-life lithium-ion batteries is essential for enabling effective battery recycling. Current approaches often rely on battery disassembly or time-consuming testing, limiting their practical use at scale. Here we report a rapid classification strategy based on X-ray fluorescence spectroscopy combined with statistical analysis. A reference dataset was established from high-quality elemental spectra collected from more than 100 end-of-life lithium-ion batteries. Statistical grouping was used to define cathode categories, which were validated by selective disassembly and complementary chemical analysis. The trained classification model was then applied to newly acquired spectra collected within seconds per battery, enabling fast identification without additional disassembly. The approach achieves high prediction accuracy across the studied dataset and demonstrates the feasibility of rapid cathode identification for battery recycling applications. Feihong Ren and colleagues report a rapid X-ray fluorescence–based method to identify the cathode chemistry of end-of-life lithium-ion batteries. This approach enables fast, non-destructive sorting and supports more efficient battery recycling.

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Cite This Study

Ren et al. (2026) studied this question.

synapsesocial.com/papers/69a7cd6ed48f933b5eed9be5https://doi.org/10.1038/s44172-026-00618-3
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