EtAlCl2 promotes the substitution of fluorine in trifluoromethyl alkenes, indicating new synthesis pathways for trisubstituted products.
Here, we report a EtAlCl2-promoted thiolation of trifluoromethyl alkenes, which leads to the complete substitution of all three fluorine atoms and affords trisubstituted products. Although the transformation proceeds through a...
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Guo et al. (2026) studied this question.
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