As a primary reaction medium, water profoundly influences the kinetics and mechanisms of chemical processes. External physical treatments, such as vibration, can alter the physicochemical properties of water, thereby modifying reaction outcomes. This study aimed to investigate the effect of vibrational iterations (I0–I7) prepared using the “crossing” technology on the kinetics of the oxidation–reduction reaction between methylene blue and ascorbic acid, a standard model for evaluating external influences. Initial characterization revealed that while pH remained stable across all samples, electrical conductivity and dissolved oxygen levels deviated significantly from the control (intact water), with oxygen concentrations measuring either higher or lower than the control. Following the dissolution of methylene blue in these iterations, absorption spectroscopy was used to monitor decolorization kinetics. Different vibrational iterations influenced distinct kinetic parameters, including the rate constant, half-reaction time, and average reaction rate. Depending on the number of processing steps used to prepare the iterations, these parameters exhibited deviations ranging from 3% to 9% compared to the control. This suggests a complex relationship between the aqueous medium’s structural–dynamic properties and the reactants’ supramolecular organization. These findings underscore the potential of vibrational iterations as a tool for modulating chemical reaction kinetics through aqueous medium engineering. Further research is needed to elucidate the underlying mechanisms and expand the applicability of this approach to other systems.
Rodionova et al. (Tue,) studied this question.