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March 5, 2026ACS Applied Materials & Interfaces3 citations

ROS-Responsive Spatiotemporal Delivery System Targeting Tendon–Bone Interface for Rotator Cuff Repair

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ZHZiqi HuoZWZeyu WangZZZeyu Zhang

Key Points

  • The aim is to develop a therapeutic strategy targeting the tendon-bone interface for enhanced healing after rotator cuff injuries.
  • Developed a ROS-responsive delivery system using polymers for targeted therapy.
  • Employed magnesium ions and kartogenin released in a controlled manner.
  • Coated the system with fibrochondrocyte cell membranes for targeted delivery.
  • Conducted in vitro assays with bone marrow mesenchymal stem cells under inflammation conditions.
  • Utilized a rat model to evaluate the efficacy of the delivery system in vivo.
  • Enhanced migration and proliferation of mesenchymal stem cells under inflammatory conditions.
  • Inhibited apoptosis and restored differentiation capacities of bone and cartilage cells.
  • Increased the proportion of M2 macrophages to promote healing.
  • Restored specific matrix deposition in fibrochondrocytes, leading to better collagen maturity.
  • Transcriptomic analysis showed reduced oxidative stress and activated anabolic pathways.

Abstract

Persistent inflammation and impaired fibrocartilage regeneration hinder the healing of the tendon-bone interface (TBI) following rotator cuff injury. To address this challenge, we propose a spatiotemporally coordinated therapeutic strategy that combines the temporal control of inflammation with targeted fibrocartilage regeneration. A multifunctional nanomedicine delivery system, designated as CMMKT, was developed using reactive oxygen species (ROS)-responsive polymers to control the release of magnesium ions (Mg2+) and kartogenin (KGN). The delivery system was coated with fibrochondrocyte cell membranes to improve spatial specificity in targeting fibrocartilage cells. CMMKT enhanced the migration and proliferation of bone marrow mesenchymal stem cells (BMSCs) in vitro under inflammatory conditions, inhibited apoptosis, restored osteogenic and chondrogenic differentiation capacities, and increased the proportion of M2 macrophages by scavenging ROS and facilitating sustained drug release. In a rat rotator cuff tear model, CMMKT-driven immunomodulation restored fibrochondrocyte-specific matrix deposition, leading to an increased collagen maturity and biomechanical strength. Transcriptomic and metabolomic analyses indicated the suppression of oxidative stress responses and the activation of anabolic pathways in fibrocartilage. Overall, this spatiotemporal coordination therapeutic concept, CMMKT, is a promising approach for TBI repair that integrates inflammatory microenvironment reprogramming with the targeted enhancement of fibrocartilage regeneration.

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Cite This Study

Huo et al. (2026) studied this question.

synapsesocial.com/papers/69a91df9d6127c7a504c1625https://doi.org/10.1021/acsami.5c21979
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