This research constructs enantiomeric lanthanide cubanes using chiral ligands, indicating potential applications in advanced materials.
Using chiral 4,4′-biphenanthrene-3,3′-diol as ligands, we constructed two pairs of enantiomers of Ln4 cubane clusters: R/S-Dy4 and R/S-Er4. Their enantiopure nature is confirmed by singlecrystal structures and mirrored circular dichroism...
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Qin et al. (2026) studied this question.
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