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March 5, 2026ACS Applied Materials & Interfaces

Unveiling the Atomic Diffusion Pathway for the In Situ Formation of Size-Controlled Intermetallic Pt on Co–N–C with Exceptional PEMFC Performance

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Authors

WLWenxuan LuSWSimin WangYXYuxuan Xu

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Overview

Demonstrates the atomic diffusion pathway for size-controlled intermetallic Pt, highlighting its potential in improving fuel cell performance.

Key Points

  • The research aims to clarify the atomic diffusion and alloying pathway for the formation of Pt-based catalysts on Co–N–C support.
  • Controlled Co amount in Co–N–C support
  • Synthesis of Pt3Fe-Co@5CoNC
  • Half-cell ORR tests
  • Membrane electrode assembly evaluation
  • DFT calculations for atomic pathway analysis
  • Achieved ultrahigh power density of 1.717 W cm^-2 at 0.429 V
  • Low Pt usage at 0.175 g kW^-1
  • Stability demonstrated with only 12.5 mV loss at 0.8 A cm^-2
  • Establishment of atomic pathway for low-coordinated Co-N3-C diffusion into L12-Pt3Fe NPs

Cite This Study

Lu et al. (2026) studied this question.

synapsesocial.com/papers/69a91e4cd6127c7a504c2193https://doi.org/10.1021/acsami.5c24941
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