Photovoltaic double-skin façades (PV-DSFs) can block solar radiation heat, mitigate air heat transfer, facilitate ventilation cooling, and generate electricity, making them a high-performance building envelope suitable for hot southern regions in summer. The thermal performance of DSFs is relatively well understood; however, with the addition of photovoltaic glass panels, the influence of design parameters is altered due to thermoelectric coupling effects. Then, the influence of design parameters on their thermoelectric performance remains unclear, hindering their design optimization. This paper establishes a mathematical model for DSFs with MATLAB (R2023a) to analyze their thermoelectric performance and the impact of design parameters. The results indicate that the daily power generation of PV-DSFs is primarily influenced by the solar radiation on the west-facing vertical surface. The wall exterior surface gains heat via longwave radiation during the day and loses heat at night, while convective heat dissipation occurs throughout the entire day, with radiative heat flux being the dominant mechanism. The power generation of photovoltaic cells is significantly influenced by their coverage ratio, while the impact of other factors can be neglected. The temperature of the wall’s exterior surface is significantly influenced by the heat storage of the outer cladding panel, the solar absorptivity of the exterior surface, and the emissivity of the interior surface. Among these factors, the heat storage of the outer cladding panel primarily affects the attenuation and delay of peak values and temperature fluctuations on the exterior surface. Meanwhile, the solar absorptivity of the exterior surface and the emissivity of the interior surface mainly influence the peak temperature of the wall’s exterior surface, with the effect becoming more pronounced when the interior surface emissivity is lower.
Li et al. (Wed,) studied this question.