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March 6, 2026Chemical Science0 citationsOpen Access

Enantioselective Synthesis of Calix4arenes with C–C Axial and Inherent Chirality via Palladium/Chiral Norbornene Cooperative Catalysis

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YYYiming YouHCHongwei ChengXHXiao Huang

Key Points

  • The research aims to achieve the enantioselective synthesis of inherently chiral calix[4]arenes.
  • Utilized palladium and chiral norbornene cooperative catalysis.
  • Focused on developing a synthetic route for chiral macrocycles.
  • Demonstrated successful formation of chiral calix[4]arenes.
  • Indicated significant potential for applications in asymmetric catalysis and chiral recognition.

Abstract

The catalytic asymmetric synthesis of inherently chiral calix4arenes, a distinct class of chiral macrocycles with significant application in asymmetric catalysis, chiral recognition and functional materials, remains a formidable challenge. Moreover,...

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Cite This Study

You et al. (2026) studied this question.

synapsesocial.com/papers/69aa70c8531e4c4a9ff5ada9https://doi.org/10.1039/d5sc10040b
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  1. 1Asymmetric Synthesis of Chiral Calix[4]arenes with Both Inherent and Axial Chirality via Cobalt‐Catalyzed Enantioselective Intermolecular C−H Annulation2024 · 3 citations
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  3. 3Organocatalytic Enantioselective Synthesis of Inherently Chiral Calix[4]arenes2024 · 8 citations
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