Demonstrates high enantioselectivity in asymmetric reactions using helical polymers, implying significant potential for green chemistry applications.
One-handed helical polyisocyanides bearing achiral benzoic acid pendants were readily synthesized via the asymmetric polymerization of achiral isocyanides using chiral Pd(II) catalysts. Despite the inexistence of any stereogenic centers, these...
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Wu et al. (2026) studied this question.
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