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March 10, 2026ChemNanoMat0 citations

Supercritical CO 2 ‐Enabled Exfoliation of SrSnO 3 Nanocrystals With Ferromagnetism

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JLJiaxin LiuBGBo GaoYLYuning Liang

Key Points

  • The research aims to develop stable room-temperature ferromagnetism in transition metal-free SrSnO3 nanocrystals.
  • Utilized supercritical CO2 to induce strain in SrSnO3 nanocrystals.
  • Analyzed the effect on crystal structure and oxygen vacancies.
  • Optimized crystal size for enhanced ferromagnetic properties.
  • Achieved room-temperature ferromagnetism with a Curie temperature of 400 K.
  • Measured saturation magnetization of 0.019 emu g−1.
  • Demonstrated a novel approach to improve structural integrity and magnetic performance.

Abstract

With the rapid development of spintronics, ferromagnetic nanomaterials have shown critical unique advantages in the fields of information storage and quantum computation. The ABO 3 ‐type perovskite oxide SrSnO 3 is expected to realize room‐temperature ferromagnetism (RTFM) due to its tunable crystal structure and unique electron arrangement. However, developing stable RTFM in transition metal‐free SrSnO 3 remains a long‐standing challenge—traditional strategies often cause lattice damage or impurity residues, failing to balance structural integrity and ferromagnetic performance. In this process, the precise supercritical CO 2 (SC CO 2 )‐induced strain effect can lead to stretching in the a‐axis direction while synchronously realizing repair of oxygen vacancies, forming a synergistic regulation of lattice structure and defect states. In addition, combining the systematic optimization of change in the crystal size to ultimately successfully realize the RTFM in SrSnO 3 ( T c = 400 K, M s = 0.019 emu g −1 ) can be presented. Therefore, this study establishes a new strategy for the development of transition metal‐free ferromagnetic materials for the application of spintronic devices at room temperature, which not only enriches the technical toolbox for designing transition metal‐free ferromagnetic perovskites but also provides a feasible pathway for their practical application in next‐generation spintronic devices.

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Cite This Study

Liu et al. (2026) studied this question.

synapsesocial.com/papers/69af952b70916d39fea4c6b3https://doi.org/10.1002/cnma.202500736
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