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March 10, 2026Advanced Synthesis & Catalysis

Recent Developments in Transition‐Metal‐Catalyzed Tandem CH Activation/Cyclization of α , ω ‐Diynes

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Authors

FXFen XuJHJia‐Qi HuoYLYa‐Peng Li

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Overview

This review highlights developments in tandem CH activation within diynes, suggesting new pathways for complex molecular construction.

Key Points

  • The aim is to detail recent advancements in transition-metal-catalyzed tandem CH activation and cyclization of diynes.
  • Examined different diynes and their application in CH activation and cyclization.
  • Discussed substrate control strategies and catalysis design.
  • Analyzed mechanistic insights and substrate scope.
  • Demonstrated enhanced site and chemoselectivity in reactions of diynes.
  • Highlighted the formation of complex structures like 1,3-dienes and polycyclic aromatic hydrocarbons.
  • Showed the importance of both alkyne units in the assembly processes.

Cite This Study

Xu et al. (2026) studied this question.

synapsesocial.com/papers/69af954870916d39fea4ca7ahttps://doi.org/10.1002/adsc.70339
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