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Research demonstrates photocatalysts enhance degradation of phthalocyanines, indicating effective design-use strategy.
In the Research Article (e23011), Erem Ahmetali, Stefan Bräse, and co-workers harness wavelength-selective photochemistry for “design-use-degradation” of network polymeric phthalocyanines. Irradiation at 368 nm triggers a [2+2] cycloaddition, generating a dibenzazepine dimer that functions as an organic bridge within the networks. 647 nm enables highly efficient sulfide oxidation alongside PET-RAFT polymerization. Remarkably, 254 nm induces controlled disassembly of the network polymeric phthalocyanines.
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Ahmetali et al. (2026) studied this question.
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