A 4,4-connected 2D POM-based complex with synergistic mixed-valence Cu I /Cu II for mild and efficient catalytic oxidation of phenols

Jiayu Sun; Si-Yu Sun; Zeyu Zhang; Mei-tong Li; Guo-Cheng Liu; Xiu-Li Wang

doi:10.1039/d6ta00645k

January 1, 2026Journal of Materials Chemistry A

A 4,4-connected 2D POM-based complex with synergistic mixed-valence Cu I /Cu II for mild and efficient catalytic oxidation of phenols

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Key Points

The study aims to synthesize a 2D POM-based complex with mixed-valence copper for enhancing catalytic oxidation of phenols.
Synthesized a 4,4-connected 2D POM-based complex
Incorporated mixed-valence copper centers
Conducted oxidation reactions at 50 °C
Achieved 98% conversion of 2,3,6-TMP to TMBQ
Obtained over 99% selectivity in the oxidation process
Completed the reaction in 13 minutes

Implication

A 4,4-connected complex demonstrates effective catalytic oxidation of phenols, suggesting a new method for organic transformations.

Abstract

A 4,4-connected 2D POM-based complex incorporating mixed-valence copper centers was successfully synthesized, exhibiting high-performance oxidation of 2,3,6-TMP to TMBQ with 98% conversion and >99% selectivity in 13 minutes at 50 °C.

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Cite This Study

Sun et al. (2026) studied this question.

synapsesocial.com/papers/69b2583896eeacc4fcec79c8 https://doi.org/10.1039/d6ta00645k

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A 4,4-connected 2D POM-based complex with synergistic mixed-valence Cu I /Cu II for mild and efficient catalytic oxidation of phenols

Key Points

Implication

Abstract

Discussion

Cite This Study

A 4,4-connected 2D POM-based complex with synergistic mixed-valence Cu I /Cu II for mild and efficient catalytic oxidation of phenols

Key Points

Implication

Abstract

Discussion

Cite This Study

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