Oily substances (oils, greases, lubricants, etc.) are among the most persistent pollutants for water. They mix with water to form emulsions that contaminate large volumes. Therefore, this project evaluated the use of porous systems (polyurethane foam) modified with polydimethylsiloxane-modified silica (SiO2/DMS) hybrid ceramics as filtration membranes at the laboratory scale for vegetable oil. The polyurethane foam was modified using sol solutions with various SiO2/PDMS ratios obtained via the sol–gel method. Tetraethyl-orthosilicate (TEOS) was used as the silica precursor. Three different polydimethylsiloxane chains were employed as the organic fragment: polydimethylsiloxane hydroxyl terminated (DMS-CH3), aminopropyl-terminated polydimethylsiloxane (DMS-N), and copolymer polydiphenylsiloxane-polydimethylsiloxane hydroxyl terminated (PDS). The siloxane chain was added at a concentration of 20–40% w/w. The modification of the porous system was determined using different characterization techniques, including infrared spectroscopy, which was used to observe the main functional groups. Optical microscopy and SEM were used to identify the hybrid ceramic deposited into the pore structure of the polyurethane sponge. Contact angle measurements revealed the hydrophobic character of the modified material. The removal capacity was evaluated by using vegetable oil as a representative oily contaminant, with values ranging from 43.42 to 96.78 g of oil per gram of adsorbent. In the case of gasoline, removal capacities between 27 and 54 g were observed. This study demonstrated the influence of hydrophobicity on vegetable oil removal, confirming that higher hydrophobicity leads to greater adsorption capacity. Nevertheless, the use of a viscous contaminant introduced challenges in the extraction process from the PS/SiO2-DMS system. Despite this limitation, the material maintained adequate removal performance for up to five reuse cycles. On the other hand, the removal capacity depends on the amount of polysiloxane chain in the ceramic, as well as the functional group, exhibiting the following behavior: DMS-N < DMS-CH3 < PDS. This study demonstrates that hydrophobicity is a key property for enhancing the removal capacity of oily substances. Moreover, the control of intermolecular interactions further strengthens this effect, as evidenced in the PS/SiO2–PDS system.
León-Reyes et al. (Wed,) studied this question.
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