Carbon monoxide ligation at single metal atom sites in a 2D manganese-cobalt coordination network: equilibrium at room temperature

Michela De Col; Danilo Comini; Stefania Baronio; Basant Roondhe; Alessandro Namar; Davide Bidoggia; Mattia Scardamaglia; Paolo Giannozzi; Erik Vesselli

doi:10.1039/d5ta10405j

January 1, 2026Journal of Materials Chemistry AOpen Access

Carbon monoxide ligation at single metal atom sites in a 2D manganese-cobalt coordination network: equilibrium at room temperature

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Key Points

The aim is to understand how carbon monoxide interacts with single metal atom sites in a specific coordination network.
Utilized a bi-metallic coordination network on graphene
Examined carbon monoxide ligation at Co(I) sites
Conducted experiments at room temperature
Carbon monoxide selectively binds to nitrogen tetra-coordinated Co(I) sites
Binding occurs at room temperature within the self-assembled structure

Implication

Research reveals carbon monoxide binds at specific metal sites in a manganese-cobalt structure, suggesting applications in catalysis.

Abstract

We find that CO ligates selectively to nitrogen tetra-coordinated Co(I) single metal atom sites at room temperature in a manganese-cobalt bi-metallic coordination network self-assembled on graphene. The bound state is...

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Cite This Study

Col et al. (2026) studied this question.

synapsesocial.com/papers/69b4fbc1b39f7826a300c2b9 https://doi.org/10.1039/d5ta10405j

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Carbon monoxide ligation at single metal atom sites in a 2D manganese-cobalt coordination network: equilibrium at room temperature

Key Points

Implication

Abstract

Discussion

Cite This Study

Carbon monoxide ligation at single metal atom sites in a 2D manganese-cobalt coordination network: equilibrium at room temperature

Key Points

Implication

Abstract

Discussion

Cite This Study

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